Thursday 9 April 2009

Chemistry and Goals of Chemists

Chemistry is a science of substances, their properties, and how and why materials combine or separate to form different substances. Atoms, molecules and compounds are the involved ones in the study of Chemistry. In other words, it is how atoms interact to form molecules and how molecules interact with each other. It also looks into the composition of substances and their properties. The outer electron orbits or shells primarily determine the chemical characteristics of a material and whether materials will chemically combine. Thus Chemistry is the study of the composition of matter and the changes that take place in that composition. If we place a bar of iron outside our window, the iron bar will soon begin to rust. If we pour vinegar on baking soda, the mixture fizzes. If we hold a sugar cube over a flame, the sugar begins to turn brown and give off steam. The goal of chemistry is to understand the composition of substances such as iron, vinegar, baking soda, and sugar and to understand what happens during the changes described here.

The term chemistry has grown out of an earlier field of study known as alchemy. Alchemy has been described as a kind of pre-chemistry, in which scholars studied the nature of matter but without the formal scientific approach that modern chemists use. The term alchemy is probably based on the Arabic name for Egypt, al-Kimia, or the "black country." Ancient scholars learned a great deal about matter, usually by trial- and-error methods. For example, the Egyptians mastered many technical procedures such as making different types of metals, manufacturing colored glass, dying cloth, and extracting oils from plants. Alchemists of the Middle Ages discovered a number of elements and compounds and perfected other chemical techniques, such as distillation and crystallization. The modern subject of chemistry did not appear, however, until the eighteenth century. At that point, scholars began to recognize that research on the nature of matter had to be conducted according to certain specific rules. Among these rules was one stating that ideas in chemistry had to be subjected to experimental tests. Nowadays keeping in view the overall significance and versatility of chemistry, we can say that:

Chemistry is a science: There is only one sanctioned procedure for determining whether a statement about matter is really chemistry: the exhaustive, inefficient, but highly successful scientific method. Chemists often arrive at new results by nonscientific means (like luck or sheer creativity), but their work isn't chemistry unless it can be reproduced and verified scientifically.

Chemistry is a systematic study: Chemists have devised several good methods for solving problems and making observations. For example, analytical chemists often use protocols (thoroughly tested recipes) for determining the concentrations of substances in a sample. Chemists use well-defined techniques like spectroscopy and chromatography to study new or unknown substances.

Chemistry is the study of the composition and properties of matter: Chemistry is the study of the composition and properties of matter as it answers questions like, "What kind of stuff is a sample made of? What does the sample look like on a molecular scale? How does the structure of the material determine its properties? How do the properties of the material change when we increase temperature, or pressure, or some other environmental variable?"

Chemistry is the study of the reactivity of substances: Chemistry is the study of the reactivity of substances as one material can be changed into another by a chemical reaction. A complex substance can by made from simpler ones. Chemical compounds can break down into simpler substances. For example, fuels burn, food cooks, leaves turn their colors in the fall, cells grow, medicines cure and it is both their chemistry and the chemistry which is concerned with the essential processes that make these changes happen. Today, the science of chemistry is often divided into four major areas: organic, inorganic, physical, and analytical chemistry. Each discipline investigates a different aspect of the properties and reactions of matter.

Organic chemistry: Organic chemistry is the study of carbon compounds. That definition sometimes puzzles beginning chemistry students because more than 100 chemical elements are known. How does it happen that one large field of chemistry is devoted to the study of only one of those elements and its compounds? The answer to that question is that carbon is a most unusual element. It is the only element whose atoms are able to combine with each other in apparently endless combinations. Many organic compounds consist of dozens, hundreds, or even thousands of carbon atoms joined to each other in a continuous chain. Other organic compounds consist of carbon chains with other carbon chains branching off them. Still other organic compounds consist of carbon atoms arranged in rings, cages, spheres, or other geometric forms. The scope of organic chemistry can be appreciated by knowing that more than 90 percent of all compounds known to science (more than 10 million compounds) are organic compounds. Organic chemistry is of special interest because it deals with many of the compounds that we encounter in our everyday lives: natural and synthetic rubber, vitamins, carbohydrates, proteins, fats and oils, cloth, plastics, paper, and most of the compounds that make up all living organisms, from simple one-cell bacteria to the most complex plants and animals.

Inorganic chemistry: Inorganic chemistry is the study of the chemistry of all the elements in the periodic table except for carbon. Like their cousins in the field of organic chemistry, inorganic chemists have provided the world with countless numbers of useful products, including fertilizers, alloys, ceramics, household cleaning products, building materials, water softening and purification systems, paints and stains, computer chips and other electronic components, and beauty products. The more than 100 elements included in the field of inorganic chemistry have a staggering variety of properties. Some are gases, others are solid, and a few are liquid. Some are so reactive that they have to be stored in special containers, while others are so inert (inactive) that they virtually never react with other elements. Some are so common they can be produced for only a few cents a pound, while others are so rare that they cost hundreds of dollars an ounce. Because of this wide variety of elements and properties, most inorganic chemists concentrate on a single element or family of elements or on certain types of reactions.

Physical chemistry: Physical chemistry is the branch of chemistry that investigates the physical properties of materials and relates these properties to the structure of the substance. Physical chemists study both organic and inorganic compounds and measure such variables as the temperature needed to liquefy a solid, the energy of the light absorbed by a substance, and the heat required to accomplish a chemical transformation. A computer is used to calculate the properties of a material and compare these assumptions to laboratory measurements. Physical chemistry is responsible for the theories and understanding of the physical phenomena utilized in organic and inorganic chemistry.

Analytical chemistry: Analytical chemistry is that field of chemistry concerned with the identification of materials and with the determination of the percentage composition of compounds and mixtures. These two lines of research are known, respectively, as qualitative analysis and quantitative analysis. Two of the oldest techniques used in analytical chemistry are gravimetric and volumetric analysis. Gravimetric analysis refers to the process by which a substance is precipitated (changed to a solid) out of solution and then dried and weighed. Volumetric analysis involves the reaction between two liquids in order to determine the composition of one or both of the liquids.

In the last half of the twentieth century, a number of mechanical systems have been developed for use in analytical research. For example, spectroscopy is the process by which an unknown sample is excited (or energized) by heating or by some other process. The radiation given off by the hot sample can then be analyzed to determine what elements are present. Various forms of spectroscopy are available (X-ray, infrared, and ultraviolet, for example) depending on the form of radiation analyzed. Other analytical techniques now in use include optical and electron microscopy, nuclear magnetic resonance (MRI; used to produce a three-dimensional image), mass spectrometry (used to identify and find out the mass of particles contained in a mixture), and various forms of chromatography (used to identify the components of mixtures).

Other fields of chemistry: The division of chemistry into four major fields is in some ways misleading and inaccurate. In the first place, each of these four fields is so large that no chemist is an authority in any one field. An inorganic chemist might specialize in the chemistry of sulfur, the chemistry of nitrogen, the chemistry of the inert gases, or in even more specialized topics. Secondly, many fields have developed within one of the four major areas, and many other fields cross two or more of the major areas. For an example of specialization, the subject of biochemistry is considered a subspecialty of organic chemistry. It is concerned with organic compounds that occur within living systems. An example of a cross-discipline subject is bioinorganic chemistry. Bioinorganic chemistry is the science dealing with the role of inorganic elements and their compounds (such as iron, copper, and sulfur) in living organisms. At present, chemists explore the boundaries of chemistry and its connections with other sciences, such as biology, environmental science, geology, mathematics, and physics. A chemist today may even have a so-called nontraditional occupation. He or she may be a pharmaceutical salesperson, a technical writer, a science librarian, an investment broker, or a patent lawyer, since discoveries by a traditional chemist may expand and diversify into a variety of fields that encompass our whole society.

Chemists have two major goals. One is to find out the composition of matter in order to learn what elements are present in a given sample and in what percentage and arrangement. This type of research is known as analysis. A second goal is to invent new substances that replicate or are different from those found in nature. This form of research is known as synthesis. In many cases, analysis leads to synthesis. That is, chemists may find that some naturally occurring substance is a good painkiller. That discovery may suggest new avenues of research that will lead to a synthetic (human-made) product similar to the natural product, but with other desirable properties (and usually lower cost). Many of the substances that chemistry has produced for human use have been developed by this process of analysis and synthesis.

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About the Author:

Dr.Badruddin Khan teaches Chemistry in the University of kashmir, srinagar, India. His E.mail is:khanbudr@yahoo.co.in

Article Source: http://www.articlesbase.com/science-articles/chemistry-and-goals-of-chemists-570403.html

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Importance of Functional Groups in Organic Chemistry

While organic chemistry is considered as the branch of chemistry in which the compounds of carbon are studied, the name organic goes back to a much earlier time in history when chemists thought that chemical compounds in living organisms were fundamentally different from those that occur in nonliving things. Their belief was that the chemicals that could be extracted from or that were produced by living organisms had a special "vitalism" or "breath of life" given to them by some supernatural being. As such, they presented fundamentally different kinds of problems than did the chemicals found in rocks, minerals, water, air, and other nonliving entities. The chemical compounds associated with living organisms were given the name organic to emphasize their connection with life. In 1828, German chemist Friedrich Wöhler, who found a very simple way to convert chemical compounds from living organisms into comparable compounds from nonliving entities, proved that this theory of vitalism was untrue. Consequently, the definition of organic chemistry changed as a result of Wöhler's research. The new definition was based on the observation that every compound discovered in living organisms had one property in common; they all contained the element carbon. As a result, the modern definition of organic chemistry, as the study of compounds of carbon, was adopted.

One important point that Wöhler's research showed was that the principles and techniques of chemistry apply equally well to compounds found in living organisms and nonliving things. Nonetheless, some important differences between organic and inorganic (not organic) compounds exist. These include the following:

1. The number of organic compounds vastly exceeds the number of inorganic compounds. The ratio of carbon-based compounds to non-carbon-based compounds is at least ten to one, with close to 10 million organic compounds known today. The reason for this dramatic difference is a special property of the carbon atom: its ability to join with other carbon atoms in very long chains, in rings, and in other kinds of geometric arrangements. It is not at all unusual for dozens, hundreds, or thousands of carbon atoms to bond to each other within a single compound—a property that no other element exhibits.

2. In general, organic compounds tend to have much lower melting and boiling points than do inorganic compounds.

3. In general, organic compounds are less likely to dissolve in water than are inorganic compounds.

4. Organic compounds are likely to be more flammable but poorer conductors of heat and electricity than are inorganic compounds.

5. Organic reactions tend to take place more slowly and to produce a much more complex set of products than do inorganic reactions.

The huge number of organic compounds requires that some system be developed for organizing them. The criterion on which those compounds are organized is the presence of various functional groups. A functional group is an arrangement of atoms that is responsible for certain characteristic physical and chemical properties in a compound. For example, one such functional group is the hydroxyl group, consisting of an oxygen atom and hydrogen atom joined to each other. It is represented by the formula —OH. All organic compounds with the same functional group are said to belong to the same organic family. Any organic compound that contains a hydroxyl group, for instance, is called an alcohol. All alcohols are similar to each other in that: (1) they contain one or more hydroxyl groups, and (2) because of those groups, they have similar physical and chemical properties. For example, alcohols tend to be more soluble in water than other organic compounds because the hydroxyl groups in the alcohol form bonds with water molecules.

The simplest organic compounds are the hydrocarbons, compounds that contain only two elements: carbon and hydrogen. The class of hydrocarbons can be divided into subgroups depending on the way in which carbon and hydrogen atoms are joined to each other. In some hydrocarbons, for example, carbon and hydrogen atoms are joined to each other only by single bonds. A single bond is a chemical bond that consists of a pair of electrons. Such hydrocarbons are known as saturated hydrocarbons. In other hydrocarbons, carbon and hydrogen atoms are joined to each other by double or triple bonds. A double bond consists of two pairs of electrons, and a triple bond consists of three pairs of electrons. The symbols used for single, double, and triple bonds, respectively, are —, =, and ?. Hydrocarbons containing double and triple bonds are said to be unsaturated. Hydrocarbons can also be open-chain or ring compounds. In an open-chain hydrocarbon, the carbon atoms are all arranged in a straight line, like a strand of spaghetti. In a ring hydrocarbon, the carbons are arranged in a continuous loop, such as a square, a pentagon, or a triangle.

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About the Author:

Dr.Badruddin Khan teaches Chemistry in the University of Kashmir, Srinagar, India

Article Source: http://www.articlesbase.com/college-and-university-articles/importance-of-functional-groups-in-organic-chemistry-623415.html

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